Corners "tt", "ss", etc., refer to transistors and are the process corners where changes in doping levels change the behavior of the transistor. Resistors and capacitors are handled separately by corners "ll", "hh", etc., for low valued resistor/capacitor and high valued resistor/capacitor. Note that the "sky130.lib.spice" file only has these backend corners combined with the nominal transistor corner. If you want to simulate, e.g., "ss" + "ll", you would need to create your own .lib file with the appropriate .include statements for the corner you want.