Also, a VPP capacitor (the models you have in your first picture) is a 'vertical parallel plate' capacitor. That's a different structure from the MIM cap for which you've linked the documentation. The xschem sky130 primitives (pr) symbol library has a symbol for the MIM cap that takes dimensions and calculates the effective capacitance. You may want to use that to see what kind of capacitance you can make with an acceptable size for your circuit. You can also calculate it yourself, looking at the table in the documentation, the capacitance for a MIM cap is 2fF per square micron (CMIMA), and 0.19fF/um for the perimeter (CMIMP). So, a 10um x 10um capacitor is about: 10x10x2 (area) + 4x10x0.19 (perimiter) = 207.6 fF