@User there aren't spice models for GPIOs provided on the pdk... you can try to extract them from the gds file, using magic, if needed... also, there are useful information about the IOs on the pdk's rtd
https://skywater-pdk.readthedocs.io/en/latest/contents/libraries/sky130_fd_io/README.html and on the caravel's datasheet... If you are mentioning analog pads the I/Os provided in caravel analog harness version (aka caravan), it is intended to interface high-frequency signals, but need to take care to the ESD sensitivity... for the analog I/O there is an spice here $(PDK_ROOT)/sky130A/libs.ref/sky130_fd_io/spice/... and you can also see chip_io.spice (caravan) and chip_io_alt.spice (caravel)...