see section 31.6.9 of the ngspice manual:
"_Negative capacitance values may occur, depending on the internal calculation. To compare_
with measured data, please just use the absolute values of the capacitance data. For an
explanation of negative values and the basics on how capacitance values are evaluated in
a BSIM model, please refer to the book BSIM4 and MOSFET Modeling for IC Simulation
_by Liu and Hu, Chapt. 5.2_".