First off, in the first screenshot you're pointing to the instance inside the cell, not the cell itself, which has the pin
VDDIO_PAD
. But otherwise, your PDK looks way out of date, because the entry should look like this:
// sky130_ef_io__vddio_hvc_pad with HV clamp connections to VDDIO and VSSIO
module sky130_ef_io__vddio_hvc_clamped_pad (AMUXBUS_A, AMUXBUS_B,
VSSA, VDDA, VSWITCH, VDDIO_Q, VCCHIB, VDDIO, VDDIO_PAD, VCCD,
VSSIO, VSSD, VSSIO_Q
);